Determining nuclear quadrupole moments of Bi and Sb from molecular data - CEA - Commissariat à l’énergie atomique et aux énergies alternatives
Journal Articles Physical Chemistry Chemical Physics Year : 2023

Determining nuclear quadrupole moments of Bi and Sb from molecular data

Abstract

An independent value of −422(3) millibarn (mb) is obtained for the nuclear quadrupole moment Q ( 209 Bi) using experimental coupling constants for diatomic BiN, BiP, BiF, BiCl, and BiI, combined with full-Dirac CCSD-T calculations of the field gradient q .

Dates and versions

cea-04435595 , version 1 (02-02-2024)

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Jean-Pierre Dognon, Pekka Pyykkö. Determining nuclear quadrupole moments of Bi and Sb from molecular data. Physical Chemistry Chemical Physics, 2023, 25 (4), pp.2758-2761. ⟨10.1039/d2cp04747k⟩. ⟨cea-04435595⟩
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