Energetics of ionic transport on Li$_w$Si$_x$P$_{1-x}$O$_y$N$_z$ amorphous and glassy electrolytes - CEA - Commissariat à l’énergie atomique et aux énergies alternatives Access content directly
Conference Papers Year : 2023

Energetics of ionic transport on Li$_w$Si$_x$P$_{1-x}$O$_y$N$_z$ amorphous and glassy electrolytes

Abstract

Lithium phosphorous oxynitride (LIPON), having an amorphous structure, was first synthesized at the Oak Ridge National Laboratory in the 1990s. Its development has arisen from the pursuit of solid electrolytes stable against lithium metal (Li) to fabricate micro-batteries employing by radio-frequency (RF) magnetron sputtering. Strictly speaking, LiPON is not thermodynamically stable against Li. However, a passivating solid electrolyte interphase emerging between Li and LiPON comprises decomposition products (Li3N and Li2O) thermodynamically stable against Li. Along with the suitable electrochemical stability, the low electronic (<10$^{-10}$ Ω$^{-1}$.cm$^{-1}$) and moderate ionic (>10$^{-6}$ Ω$^{-1}$.cm$^{-1}$) conductivity have been also refereed as key properties for its applications as thin-film electrolytes.
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Dates and versions

cea-04208866 , version 1 (15-09-2023)

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  • HAL Id : cea-04208866 , version 1

Cite

Rafael Bianchini Nuernberg, Annie-Kim Landry, Racha Bayzou, Frédéric Le Cras, Olivier Lafon. Energetics of ionic transport on Li$_w$Si$_x$P$_{1-x}$O$_y$N$_z$ amorphous and glassy electrolytes. LiBD2023 - Lithium Batteries Discussions "Electrode Materials", Jun 2023, Arcachon, France. ⟨cea-04208866⟩
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