A 3D-printed device for in situ monitoring of an organic redox-flow battery via NMR/MRI - CEA - Commissariat à l’énergie atomique et aux énergies alternatives Access content directly
Journal Articles Analytical Chemistry Year : 2023

A 3D-printed device for in situ monitoring of an organic redox-flow battery via NMR/MRI

Abstract

A mini organic redox-flow battery pluggable on the basis of a high-resolution NMR probehead has been conceived and built mainly by 3D printing. This device allows the realization of all modern spectroscopy experiments as well as imaging experiments. It has been tested for the real-time monitoring of redox cycling of 9,10-Anthraquinone-2,7-disulfonic acid disodium salt (2,7-AQDS) in acidic conditions, which has revealed the preponderant role of dimerization in the processes of oxidation and reduction. Determination of the thermodynamic properties of homo-and heterodimer formation through quantum chemical, multilevel modeling workflows confirm our hypotheses about the molecular processes occurring during charge and discharge.
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Dates and versions

cea-04065111 , version 1 (11-04-2023)

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Borja Caja-Munoz, Kévin Chighine, Jean-Pierre Dognon, Lionel Dubois, Patrick Berthault. A 3D-printed device for in situ monitoring of an organic redox-flow battery via NMR/MRI. Analytical Chemistry, 2023, 95 (14), pp.6020-6028. ⟨10.1021/acs.analchem.3c00051⟩. ⟨cea-04065111⟩
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