Molecular Characterization of Actinide Oxocations from Protactinium to Plutonium - CEA - Commissariat à l’énergie atomique et aux énergies alternatives
Communication Dans Un Congrès Année : 2006

Molecular Characterization of Actinide Oxocations from Protactinium to Plutonium

Résumé

This presentation addresses the structural characterization by EXAFS of actinide cations at oxidation states (V) and (VI) as one walks across the periodic table from Z = 91 (protactinium) to Z = 94 (plutonium). A structural comparison between Pa, U, Np and Pu oxocations in aqueous solution at formal oxidation states (V) and (VI) is carried out. These results are corroborated by quantum chemical and molecular dynamics calculations.
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Dates et versions

cea-04695770 , version 1 (12-09-2024)

Identifiants

  • HAL Id : cea-04695770 , version 1

Citer

C. Den Auwer, Philippe Guilbaud, D. Guillaumont, P. Moisy, V. Digandomenico, et al.. Molecular Characterization of Actinide Oxocations from Protactinium to Plutonium. X-Ray Absorption Fine Structure - XAFS13, Jul 2006, Stanford (CA), USA, United States. pp.184-186. ⟨cea-04695770⟩
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