Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones - CEA - Commissariat à l’énergie atomique et aux énergies alternatives Access content directly
Journal Articles Chemical Communications Year : 2022

Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones

Abstract

A transfer hydrosilylation of ketones employing silyl formates as hydrosilane surrogates under mild conditions is presented. A total of 24 examples of ketones have been successfully converted to their corresponding silyl ethers with 61–99% yields in the presence of a PNHP-based ruthenium catalyst and silyl formate reagent. The crucial role of the ligand for the transformation is demonstrated.
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Dates and versions

cea-03662659 , version 1 (05-10-2022)

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Attribution - NonCommercial

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Rafael Martin Romero, Neethu Thyagarajan, Nora Hellou, Clément Chauvier, Timothé Godou, et al.. Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones. Chemical Communications, 2022, 58 (43), pp.6308-6311. ⟨10.1039/D2CC00666A⟩. ⟨cea-03662659⟩
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