Transfer Hydrosilylation. Silyl Formates as Surrogates of Hydrosilanes and Their Application in the Transfer Hydrosilylation of Aldehydes - CEA - Commissariat à l’énergie atomique et aux énergies alternatives Access content directly
Journal Articles Angewandte Chemie International Edition Year : 2016

Transfer Hydrosilylation. Silyl Formates as Surrogates of Hydrosilanes and Their Application in the Transfer Hydrosilylation of Aldehydes

Abstract

Silyl formates are investigated for the first time as surrogates of hydrosilanes. In the presence of a well-defined ruthenium catalyst, these reagents are shown to promote the chemoselective reduction of a variety of aldehydes by transfer hydrosilylation. Mechanistic investigations have shown that genuine hydrosilane species are avoided during catalysis. The mechanism involves a sequence of decarboxylation/insertion/ transmetallation steps.
Fichier principal
Vignette du fichier
Anie.201607201.pdf (753.38 Ko) Télécharger le fichier
Origin : Publication funded by an institution
Loading...

Dates and versions

cea-01391214 , version 1 (21-01-2019)

Identifiers

Cite

Clément Chauvier, Pierre Thuéry, Thibault Cantat. Transfer Hydrosilylation. Silyl Formates as Surrogates of Hydrosilanes and Their Application in the Transfer Hydrosilylation of Aldehydes. Angewandte Chemie International Edition, 2016, 55, pp.14096 - 14100. ⟨10.1002/anie.201607201⟩. ⟨cea-01391214⟩
78 View
331 Download

Altmetric

Share

Gmail Facebook X LinkedIn More