Pre-treatment of hydrolysable nuclear organic liquids prior to their waste management: Solid impregnation of vegetable oil on surfactant-grafted clay particles
Résumé
In the context of advancing nuclear waste management techniques, this study delves into the novel use of surfactant-grafted clay particles for pre-treating hydrolysable nuclear organic liquids. Our research explores the potential of modified clay materials in immobilizing vegetable oil, a surrogate for complex nuclear waste. We systematically
investigate the adsorption capabilities of various clays, including metakaolin, diatomaceous earth and sepiolite, when grafted with two surfactants: cetyltrimethylammonium bromide (CTAB) as cationic surfactant and decyl glucoside
(DG) as non-ionic surfactant. This study employs comprehensive characterization techniques to assess the physicochemical transformations in clays post surfactantgrafting. Grafting was initially highlighted by TGA, where the breakdown of surfactants can be observed. This is also evidenced by measurements of the ζ-potential, which
demonstrate a reduction in surface charge upon the addition of the cationic surfactant, excepted for sepiolite for which the surface charge did not change. The increase in ζpotential was about 126% for modified metakaolin. Additionally, Washburn measurements indicate that the grafting process converts hydrophilic particles into hydrophobic ones. The oil absorption tests indicated that the CTAB-grafted sepiolite demonstrated superior characteristics, notably exhibiting no oil rejection. Consequently, this specifically synthesized powder was utilized in a two-step process consisting in preimpregnation of oil up to 20%v of vegetable oil prior to its immobilization within a geopolymer matrix. Furthermore, the outcomes of the leaching tests revealed that the vegetable oil remained effectively confined within the immobilization matrix, ensuring its retention. The research contributes to the goal of enhancing hydrolysable nuclear waste management practices, ensuring long-term sustainability and environmental safety
Domaines
ChimieOrigine | Fichiers produits par l'(les) auteur(s) |
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