A (NiMnCo)-Metal-Organic Framework (MOF) as active material for Lithium-ion battery electrodes - CEA - Commissariat à l’énergie atomique et aux énergies alternatives
Article Dans Une Revue Science and Technology for Energy Transition Année : 2023

A (NiMnCo)-Metal-Organic Framework (MOF) as active material for Lithium-ion battery electrodes

Résumé

A (NiMnCo)-Metal-Organic Framework and its oxidized and pyrolysed derivatives have been tested as electrode materials for lithium-ion batteries. Materials have been fully characterized by Scanning Electron Microscopy (SEM), powder X-Ray Diffraction (XRD), Thermogravimetric Analyses (TGA), Infrared (IR) spectroscopy and electrochemical properties have been determined in coin cells using lithium metal as the counter electrode. Studies have revealed specific capacities of 860 mAh g$^{−1}$ and 800 mAh g$^{−1}$ at 15 mA g$^{−1}$ respectively for the MOF and the oxide (690 and 190 mAh g$^{−1}$ after 50 cycles) whereas the corresponding pyrolysed compound has shown limited electrochemical performances. Ex situ XRD has been performed to highlight the evolution of the material structure during cycling. These results show that electrochemical storage is based on a conversion reaction.
Fichier principal
Vignette du fichier
stet20230084.pdf (466.98 Ko) Télécharger le fichier
Origine Fichiers éditeurs autorisés sur une archive ouverte
Licence

Dates et versions

cea-04290926 , version 1 (17-11-2023)

Licence

Identifiants

Citer

Marine Cognet, Thibaut Gutel, David Peralta, Jerome Maynadié, J Cambedouzou, et al.. A (NiMnCo)-Metal-Organic Framework (MOF) as active material for Lithium-ion battery electrodes. Science and Technology for Energy Transition, 2023, Synthesis and characterisation of porous materials for clean energy application, 78, pp.33. ⟨10.2516/stet/2023031⟩. ⟨cea-04290926⟩
106 Consultations
198 Téléchargements

Altmetric

Partager

More