%0 Journal Article %T Additive-free selective methylation of secondary amines with formic acid over a Pd/In$_2$O$_3$ catalyst %+ Laboratoire de Chimie Moléculaire et de Catalyse pour l'Energie (ex LCCEF) (LCMCE) %+ Laboratoire Edifices Nanométriques (LEDNA) %A Genre, Caroline %A Benaissa, Idir %A Godou, Timothé %A Pinault, Mathieu %A Cantat, Thibault %Z Fondation de la Maison de la Chimie (Paris, France) %< avec comité de lecture %@ 2044-4753 %J Catalysis Science & Technology %I Royal Society of Chemistry %V 12 %P 57-61 %8 2021-12-03 %D 2021 %R 10.1039/D1CY01626A %Z Chemical Sciences/Material chemistry %Z Chemical Sciences/CatalysisJournal articles %X Formic acid is used as the sole carbon and hydrogen source in the methylation of aromatic and aliphatic amines to methylamines. The reaction proceeds via a formylation/transfer hydrogenation pathway over a solid Pd/In$_2$O$_3$ catalyst without the need for any additive. %G English %2 https://cea.hal.science/cea-03478547/document %2 https://cea.hal.science/cea-03478547/file/Genre_CatSciTech2022_V0.pdf %L cea-03478547 %U https://cea.hal.science/cea-03478547 %~ CEA %~ CNRS %~ OPENAIRE %~ PUBNIMBE %~ INC-CNRS %~ IRAMIS-NIMBE %~ CEA-UPSAY %~ UNIV-PARIS-SACLAY %~ TEST-HALCNRS %~ UNIVERSITE-PARIS-SACLAY %~ GS-ENGINEERING %~ IRAMIS %~ GS-CHIMIE %~ GS-PHYSIQUE %~ INSTITUT-SCIENCES-LUMIERE %~ TEST2-HALCNRS