Unlocking the Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with Superbases - CEA - Commissariat à l’énergie atomique et aux énergies alternatives Access content directly
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Unlocking the Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with Superbases

Abstract

The efficient synthesis of hydrosilanes by catalytic ydrogenolysis of chlorosilanes is described, using an Iridum (III) pincer catalyst. A careful selection of a nitrogen base (incl. sterically hindered guanidines and phosphazenes) can unlock the preparation of Me3SiH, Et3SiH and Me2SiHCl in high yield (up to 98%), directly from their corresponding chlorosilanes.
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cea-03204999 , version 1 (22-04-2021)

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Attribution - NonCommercial - NoDerivatives

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Gabriel Durin, Jean-Claude Berthet, Emmanuel Nicolas, Thibault Cantat. Unlocking the Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with Superbases. 2021. ⟨cea-03204999⟩
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