%0 Journal Article %T Thermochemical effect of fission products on sodium - MOX fuel reaction: The case of niobium %+ CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)) %+ Chalmers University of Technology [Göteborg] %A Costin, D., T. %A Desgranges, L. %A Cabello-Ortiga, V. %A Hedberg, M. %A Hallerod, J. %A Retegan, T. %A Ekberg, C. %Z The authors are indebted for AREVA and Électricité de France for their financial support. %< avec comité de lecture %@ 0022-3115 %J Journal of Nuclear Materials %I Elsevier %V 500 %P 361-365 %8 2017 %D 2017 %R 10.1016/j.jnucmat.2018.01.016 %K reaction MOX-Na %K ASTRID %K Fission products %K Niobium %Z Physics [physics]/Nuclear Experiment [nucl-ex] %Z Physics [physics]/Nuclear Theory [nucl-th]Journal articles %X The influence of niobium on the sodium MOX fuel chemical interaction was studied by different heat treatments of airtight capsules containing fresh MOX, sodium and a niobium strip. The characterisation results evidenced a two-step process with first MOX oxidation and then MOX reduction. This result was interpreted by considering the formation of sodium niobiate that captures oxygen from the MOX. This interpretation is used to discuss the influence of niobium as fission product on the sodium –irradiated MOX fuel reaction. %G English %2 https://cea.hal.science/cea-02421737/document %2 https://cea.hal.science/cea-02421737/file/201700002680.pdf %L cea-02421737 %U https://cea.hal.science/cea-02421737 %~ CEA %~ DEN