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              <p>Diverses techniques d'hyperpolarisation permettent d'aboutir à une population des états despins nucléaires éloignée de celle de l'équilibre thermodynamique réglée par la loi deBoltzmann. Parmi elles, la méthode SABRE, acronyme de Signal Amplification by ReversibleExchange, est une méthode simple à mettre en œuvre fondée sur les propriétés très particulièresdu parahydrogène. Des taux d'augmentation du signal de plusieurs centaines par rapport àl'équilibre thermodynamique peuvent être obtenus. Pour discriminer des moléculeshyperpolarisées par la méthode SABRE en solution, on peut appliquer des séquences 2Dclassiques, dans lesquelles au moins une acquisition est requise pour chaque temps d'évolutionnécessaire à la reconstitution de la dimension indirecte. Cependant, ceci est difficile lorsque lecaractère hyperpolarisé est irréversiblement perdu au cours de l'acquisition. Une solutionadaptée à cette situation est d'acquérir en une seule fois l'ensemble des données nécessaires àl'acquisition du spectre 2D, en moins d'une seconde, au moyen de séquences ultra-rapidesutilisant un encodage spatio-temporel. Je traiterai ici des développements méthodologiques àbase de séquences ultra-rapides COSy et DOSy, appliquées à un mélange de molécules enconcentration millimolaire ou sub-millimolaire en solution.</p>
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